This page lists the head-to-head record of Valencia vs Villarreal including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | Villarreal | Valencia | Draws |
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| Total Matches | 59 | 23 | 23 | 13 |
| At El Madrigal | 30 | 7 | 17 | 6 |
| At Mestalla | 29 | 16 | 6 | 7 |
| UEFA Europa League Matches | 4 | 0 | 3 | 1 |
| Cup Matches | 4 | 1 | 2 | 1 |
| Primera Matches | 51 | 22 | 18 | 11 |
| Total Goals Scored | 149 | 73 | 76 | |
Last 50 Villarreal vs Valencia Matches
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| 2025 25 October | | Primera | Valencia | 0 - 2 | Villarreal |
| 2025 15 February | | Primera | Villarreal | 1 - 1 | Valencia |
| 2024 31 August | | Primera | Valencia | 1 - 1 | Villarreal |
| 2024 17 March | | Primera | Villarreal | 1 - 0 | Valencia |
| 2024 2 January | | Primera | Valencia | 3 - 1 | Villarreal |
| 2023 3 May | | Primera | Valencia | 1 - 1 | Villarreal |
| 2022 31 December | | Primera | Villarreal | 2 - 1 | Valencia |
| 2022 19 April | | Primera | Villarreal | 2 - 0 | Valencia |
| 2021 30 October | | Primera | Valencia | 2 - 0 | Villarreal |
| 2021 5 March | | Primera | Valencia | 2 - 1 | Villarreal |
| 2020 18 October | | Primera | Villarreal | 2 - 1 | Valencia |
| 2020 28 June | | Primera | Villarreal | 2 - 0 | Valencia |
| 2019 30 November | | Primera | Valencia | 2 - 1 | Villarreal |
| 2019 18 April | | UEFA Europa League | Valencia | 2 - 0 | Villarreal |
| 2019 11 April | | UEFA Europa League | Villarreal | 1 - 3 | Valencia |
| 2019 26 January | | Primera | Valencia | 3 - 0 | Villarreal |
| 2018 23 September | | Primera | Villarreal | 0 - 0 | Valencia |
| 2018 5 May | | Primera | Villarreal | 1 - 0 | Valencia |
| 2017 23 December | | Primera | Valencia | 0 - 1 | Villarreal |
| 2017 21 May | | Primera | Valencia | 1 - 3 | Villarreal |
| 2017 21 January | | Primera | Villarreal | 0 - 2 | Valencia |
| 2016 1 May | | Primera | Valencia | 0 - 2 | Villarreal |
| 2015 31 December | | Primera | Villarreal | 1 - 0 | Valencia |
| 2015 5 April | | Primera | Valencia | 0 - 0 | Villarreal |
| 2014 2 November | | Primera | Villarreal | 1 - 3 | Valencia |
| 2014 23 March | | Primera | Valencia | 2 - 1 | Villarreal |
| 2013 27 October | | Primera | Villarreal | 4 - 1 | Valencia |
| 2012 5 May | | Primera | Valencia | 1 - 0 | Villarreal |
| 2012 8 January | | Primera | Villarreal | 2 - 2 | Valencia |
| 2011 10 April | | Primera | Valencia | 5 - 0 | Villarreal |
| 2011 6 January | | Cup | Villarreal | 4 - 2 | Valencia |
| 2010 21 December | | Cup | Valencia | 0 - 0 | Villarreal |
| 2010 20 November | | Primera | Villarreal | 1 - 1 | Valencia |
| 2010 8 May | | Primera | Villarreal | 2 - 0 | Valencia |
| 2010 17 January | | Primera | Valencia | 4 - 1 | Villarreal |
| 2009 23 May | | Primera | Villarreal | 3 - 1 | Valencia |
| 2009 10 January | | Primera | Valencia | 3 - 3 | Villarreal |
| 2008 19 January | | Primera | Villarreal | 3 - 0 | Valencia |
| 2007 26 August | | Primera | Valencia | 0 - 3 | Villarreal |
| 2007 26 May | | Primera | Valencia | 2 - 3 | Villarreal |
| 2007 7 January | | Primera | Villarreal | 0 - 1 | Valencia |
| 2006 21 March | | Primera | Valencia | 1 - 1 | Villarreal |
| 2006 10 January | | Cup | Valencia | 1 - 0 | Villarreal |
| 2006 3 January | | Cup | Villarreal | 0 - 2 | Valencia |
| 2005 4 November | | Primera | Villarreal | 1 - 0 | Valencia |
| 2005 22 January | | Primera | Villarreal | 3 - 1 | Valencia |
| 2004 29 August | | Primera | Valencia | 2 - 1 | Villarreal |
| 2004 13 May | | Primera | Villarreal | 2 - 1 | Valencia |
| 2004 5 May | | UEFA Europa League | Valencia | 1 - 0 | Villarreal |
| 2004 21 April | | UEFA Europa League | Villarreal | 0 - 0 | Valencia |
Biggest Villarreal Victory vs Valencia
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| 2007 26 August | | Primera | Valencia | 0 - 3 | Villarreal |
Biggest Valencia Victory vs Villarreal
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| 2011 10 April | | Primera | Valencia | 5 - 0 | Villarreal |
Biggest Villarreal Defeat vs Valencia
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| 2011 10 April | | Primera | Valencia | 5 - 0 | Villarreal |
Biggest Valencia Defeat vs Villarreal
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| 2007 26 August | | Primera | Valencia | 0 - 3 | Villarreal |
Last 5 Villarreal Home Matches
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| 2025 1 November | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
| 2025 21 October | | UEFA Champions League | Villarreal | 0 - 2 | Manchester City |
| 2025 18 October | | Primera | Villarreal | 2 - 2 | Real Betis |
| 2025 1 October | | UEFA Champions League | Villarreal | 2 - 2 | Juventus |
| 2025 27 September | | Primera | Villarreal | 1 - 0 | Athletic Club |
Last 5 Valencia Home Matches
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| 2025 25 October | | Primera | Valencia | 0 - 2 | Villarreal |
| 2025 30 September | | Primera | Valencia | 1 - 2 | Real Oviedo |
| 2025 20 September | | Primera | Valencia | 2 - 0 | Athletic Club |
| 2025 29 August | | Primera | Valencia | 3 - 0 | Getafe |
| 2025 29 August | | Primera | Valencia | 3 - 0 | Getafe |
Last 5 Villarreal Away Matches
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| 2025 29 October | | Cup | Ciudad de Lucena | 0 - 6 | Villarreal |
| 2025 25 October | | Primera | Valencia | 0 - 2 | Villarreal |
| 2025 4 October | | Primera | Real Madrid | 3 - 1 | Villarreal |
| 2025 23 September | | Primera | Sevilla | 1 - 2 | Villarreal |
| 2025 16 September | | UEFA Champions League | Tottenham Hotspur | 1 - 0 | Villarreal |
Last 5 Valencia Away Matches
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| 2025 1 November | | Primera | Real Madrid | 4 - 0 | Valencia |
| 2025 28 October | | Cup | Maracena | 0 - 5 | Valencia |
| 2025 20 October | | Primera | Deportivo Alaves | 0 - 0 | Valencia |
| 2025 4 October | | Primera | Girona | 2 - 1 | Valencia |
| 2025 23 September | | Primera | Espanyol | 2 - 2 | Valencia |