This page lists the head-to-head record of Villarreal vs Rayo Vallecano including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | Rayo Vallecano | Villarreal | Draws |
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| Total Matches | 28 | 6 | 17 | 5 |
| At Teresa Rivero | 14 | 2 | 10 | 2 |
| At El Madrigal | 14 | 4 | 7 | 3 |
| Cup Matches | 1 | 0 | 1 | 0 |
| Segunda Matches | 2 | 1 | 1 | 0 |
| Primera Matches | 25 | 5 | 15 | 5 |
| Total Goals Scored | 90 | 33 | 57 | |
Last 50 Rayo Vallecano vs Villarreal Matches
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| 2025 1 November | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
| 2025 22 February | | Primera | Rayo Vallecano | 0 - 1 | Villarreal |
| 2024 18 December | | Primera | Villarreal | 1 - 1 | Rayo Vallecano |
| 2024 28 April | | Primera | Villarreal | 3 - 0 | Rayo Vallecano |
| 2023 24 September | | Primera | Rayo Vallecano | 1 - 1 | Villarreal |
| 2023 28 May | | Primera | Rayo Vallecano | 2 - 1 | Villarreal |
| 2023 30 January | | Primera | Villarreal | 0 - 1 | Rayo Vallecano |
| 2022 12 May | | Primera | Rayo Vallecano | 1 - 5 | Villarreal |
| 2021 12 December | | Primera | Villarreal | 2 - 0 | Rayo Vallecano |
| 2020 29 January | | Cup | Rayo Vallecano | 0 - 2 | Villarreal |
| 2019 17 March | | Primera | Villarreal | 3 - 1 | Rayo Vallecano |
| 2018 11 November | | Primera | Rayo Vallecano | 2 - 2 | Villarreal |
| 2016 17 April | | Primera | Rayo Vallecano | 2 - 1 | Villarreal |
| 2015 6 December | | Primera | Villarreal | 2 - 1 | Rayo Vallecano |
| 2015 15 February | | Primera | Rayo Vallecano | 2 - 0 | Villarreal |
| 2014 21 September | | Primera | Villarreal | 4 - 2 | Rayo Vallecano |
| 2014 10 May | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
| 2014 6 January | | Primera | Rayo Vallecano | 2 - 5 | Villarreal |
| 2012 25 March | | Primera | Rayo Vallecano | 0 - 2 | Villarreal |
| 2011 29 October | | Primera | Villarreal | 2 - 0 | Rayo Vallecano |
| 2003 1 March | | Primera | Villarreal | 2 - 1 | Rayo Vallecano |
| 2002 5 October | | Primera | Rayo Vallecano | 2 - 2 | Villarreal |
| 2002 11 January | | Primera | Villarreal | 1 - 1 | Rayo Vallecano |
| 2001 25 August | | Primera | Rayo Vallecano | 1 - 2 | Villarreal |
| 2001 27 January | | Primera | Rayo Vallecano | 0 - 1 | Villarreal |
| 2000 9 September | | Primera | Villarreal | 1 - 5 | Rayo Vallecano |
| 1998 24 January | | Segunda | Villarreal | 3 - 0 | Rayo Vallecano |
| 1997 13 September | | Segunda | Rayo Vallecano | 5 - 0 | Villarreal |
Biggest Rayo Vallecano Victory vs Villarreal
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| 1997 13 September | | Segunda | Rayo Vallecano | 5 - 0 | Villarreal |
Biggest Villarreal Victory vs Rayo Vallecano
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| 2014 10 May | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
Biggest Rayo Vallecano Defeat vs Villarreal
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| 2014 10 May | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
Biggest Villarreal Defeat vs Rayo Vallecano
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| 1997 13 September | | Segunda | Rayo Vallecano | 5 - 0 | Villarreal |
Last 5 Rayo Vallecano Home Matches
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| 2025 18 December | | Europa Conference League | Rayo Vallecano | 3 - 0 | Drita |
| 2025 15 December | | Primera | Rayo Vallecano | 0 - 0 | Real Betis |
| 2025 1 December | | Primera | Rayo Vallecano | 1 - 1 | Valencia |
| 2025 9 November | | Primera | Rayo Vallecano | 0 - 0 | Real Madrid |
| 2025 6 November | | Europa Conference League | Rayo Vallecano | 3 - 2 | Lech Poznan |
Last 5 Villarreal Home Matches
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| 2025 10 December | | UEFA Champions League | Villarreal | 2 - 3 | Copenhagen |
| 2025 6 December | | Primera | Villarreal | 2 - 0 | Getafe |
| 2025 22 November | | Primera | Villarreal | 2 - 1 | Mallorca |
| 2025 1 November | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
| 2025 21 October | | UEFA Champions League | Villarreal | 0 - 2 | Manchester City |
Last 5 Rayo Vallecano Away Matches
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| 2025 11 December | | Europa Conference League | Jagiellonia Bialystok | 1 - 2 | Rayo Vallecano |
| 2025 7 December | | Primera | Espanyol | 1 - 0 | Rayo Vallecano |
| 2025 4 December | | Cup | Real Avila | 1 - 1 | Rayo Vallecano |
| 2025 27 November | | Europa Conference League | Slovan Bratislava | 2 - 1 | Rayo Vallecano |
| 2025 23 November | | Primera | Real Oviedo | 0 - 0 | Rayo Vallecano |
Last 5 Villarreal Away Matches
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| 2025 17 December | | Cup | Racing Santander | 2 - 1 | Villarreal |
| 2025 3 December | | Cup | Antoniano | 0 - 0 | Villarreal |
| 2025 30 November | | Primera | Real Sociedad | 2 - 3 | Villarreal |
| 2025 25 November | | UEFA Champions League | Borussia Dortmund | 4 - 0 | Villarreal |
| 2025 8 November | | Primera | Espanyol | 0 - 2 | Villarreal |