This page lists the head-to-head record of Villarreal vs Rayo Vallecano including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | Rayo Vallecano | Villarreal | Draws |
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| Total Matches | 27 | 6 | 16 | 5 |
| At Teresa Rivero | 13 | 2 | 9 | 2 |
| At El Madrigal | 14 | 4 | 7 | 3 |
| Cup Matches | 1 | 0 | 1 | 0 |
| Segunda Matches | 2 | 1 | 1 | 0 |
| Primera Matches | 24 | 5 | 14 | 5 |
| Total Goals Scored | 86 | 33 | 53 | |
Last 50 Rayo Vallecano vs Villarreal Matches
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| 2025 22 February | | Primera | Rayo Vallecano | 0 - 1 | Villarreal |
| 2024 18 December | | Primera | Villarreal | 1 - 1 | Rayo Vallecano |
| 2024 28 April | | Primera | Villarreal | 3 - 0 | Rayo Vallecano |
| 2023 24 September | | Primera | Rayo Vallecano | 1 - 1 | Villarreal |
| 2023 28 May | | Primera | Rayo Vallecano | 2 - 1 | Villarreal |
| 2023 30 January | | Primera | Villarreal | 0 - 1 | Rayo Vallecano |
| 2022 12 May | | Primera | Rayo Vallecano | 1 - 5 | Villarreal |
| 2021 12 December | | Primera | Villarreal | 2 - 0 | Rayo Vallecano |
| 2020 29 January | | Cup | Rayo Vallecano | 0 - 2 | Villarreal |
| 2019 17 March | | Primera | Villarreal | 3 - 1 | Rayo Vallecano |
| 2018 11 November | | Primera | Rayo Vallecano | 2 - 2 | Villarreal |
| 2016 17 April | | Primera | Rayo Vallecano | 2 - 1 | Villarreal |
| 2015 6 December | | Primera | Villarreal | 2 - 1 | Rayo Vallecano |
| 2015 15 February | | Primera | Rayo Vallecano | 2 - 0 | Villarreal |
| 2014 21 September | | Primera | Villarreal | 4 - 2 | Rayo Vallecano |
| 2014 10 May | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
| 2014 6 January | | Primera | Rayo Vallecano | 2 - 5 | Villarreal |
| 2012 25 March | | Primera | Rayo Vallecano | 0 - 2 | Villarreal |
| 2011 29 October | | Primera | Villarreal | 2 - 0 | Rayo Vallecano |
| 2003 1 March | | Primera | Villarreal | 2 - 1 | Rayo Vallecano |
| 2002 5 October | | Primera | Rayo Vallecano | 2 - 2 | Villarreal |
| 2002 11 January | | Primera | Villarreal | 1 - 1 | Rayo Vallecano |
| 2001 25 August | | Primera | Rayo Vallecano | 1 - 2 | Villarreal |
| 2001 27 January | | Primera | Rayo Vallecano | 0 - 1 | Villarreal |
| 2000 9 September | | Primera | Villarreal | 1 - 5 | Rayo Vallecano |
| 1998 24 January | | Segunda | Villarreal | 3 - 0 | Rayo Vallecano |
| 1997 13 September | | Segunda | Rayo Vallecano | 5 - 0 | Villarreal |
Biggest Rayo Vallecano Victory vs Villarreal
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| 1997 13 September | | Segunda | Rayo Vallecano | 5 - 0 | Villarreal |
Biggest Villarreal Victory vs Rayo Vallecano
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| 2014 10 May | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
Biggest Rayo Vallecano Defeat vs Villarreal
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| 2014 10 May | | Primera | Villarreal | 4 - 0 | Rayo Vallecano |
Biggest Villarreal Defeat vs Rayo Vallecano
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| 1997 13 September | | Segunda | Rayo Vallecano | 5 - 0 | Villarreal |
Last 5 Rayo Vallecano Home Matches
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| 2025 2 October | | Europa Conference League | Rayo Vallecano | 2 - 0 | Shkendija |
| 2025 28 September | | Primera | Rayo Vallecano | 0 - 1 | Sevilla |
| 2025 21 September | | Primera | Rayo Vallecano | 1 - 1 | Celta Vigo |
| 2025 31 August | | Primera | Rayo Vallecano | 1 - 1 | Barcelona |
| 2025 28 August | | Europa Conference League | Rayo Vallecano | 4 - 0 | Neman Grodno |
Last 5 Villarreal Home Matches
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| 2025 1 October | | UEFA Champions League | Villarreal | 2 - 2 | Juventus |
| 2025 27 September | | Primera | Villarreal | 1 - 0 | Athletic Club |
| 2025 20 September | | Primera | Villarreal | 2 - 1 | Osasuna |
| 2025 24 August | | Primera | Villarreal | 5 - 0 | Girona |
| 2025 15 August | | Primera | Villarreal | 2 - 0 | Real Oviedo |
Last 5 Rayo Vallecano Away Matches
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| 2025 5 October | | Primera | Real Sociedad | 0 - 1 | Rayo Vallecano |
| 2025 24 September | | Primera | Atletico Madrid | 3 - 2 | Rayo Vallecano |
| 2025 14 September | | Primera | Osasuna | 2 - 0 | Rayo Vallecano |
| 2025 25 August | | Primera | Athletic Club | 1 - 0 | Rayo Vallecano |
| 2025 25 August | | Primera | Athletic Club | 1 - 0 | Rayo Vallecano |
Last 5 Villarreal Away Matches
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| 2025 4 October | | Primera | Real Madrid | 3 - 1 | Villarreal |
| 2025 23 September | | Primera | Sevilla | 1 - 2 | Villarreal |
| 2025 16 September | | UEFA Champions League | Tottenham Hotspur | 1 - 0 | Villarreal |
| 2025 13 September | | Primera | Atletico Madrid | 2 - 0 | Villarreal |
| 2025 31 August | | Primera | Celta Vigo | 1 - 1 | Villarreal |