This page lists the head-to-head record of Ajax vs PSV Eindhoven including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | PSV Eindhoven | Ajax | Draws |
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| Total Matches | 69 | 28 | 22 | 19 |
| At Philips Stadion | 35 | 12 | 15 | 8 |
| At Amsterdam Arena | 34 | 16 | 7 | 11 |
| Cup Matches | 4 | 1 | 2 | 1 |
| Eredivisie Matches | 65 | 27 | 20 | 18 |
| Total Goals Scored | 214 | 115 | 99 | |
Last 50 PSV Eindhoven vs Ajax Matches
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| 2025 21 September | | Eredivisie | PSV | 2 - 2 | Ajax |
| 2025 30 March | | Eredivisie | PSV | 0 - 2 | Ajax |
| 2024 2 November | | Eredivisie | Ajax | 3 - 2 | PSV |
| 2024 3 February | | Eredivisie | Ajax | 1 - 1 | PSV |
| 2023 29 October | | Eredivisie | PSV | 5 - 2 | Ajax |
| 2023 30 April | | Cup | Ajax | 1 - 1 | PSV |
| 2023 23 April | | Eredivisie | PSV | 3 - 0 | Ajax |
| 2022 6 November | | Eredivisie | Ajax | 1 - 2 | PSV |
| 2022 17 April | | Cup | PSV | 2 - 1 | Ajax |
| 2022 23 January | | Eredivisie | PSV | 1 - 2 | Ajax |
| 2021 24 October | | Eredivisie | Ajax | 5 - 0 | PSV |
| 2021 28 February | | Eredivisie | PSV | 1 - 1 | Ajax |
| 2021 10 February | | Cup | Ajax | 2 - 1 | PSV |
| 2021 10 January | | Eredivisie | Ajax | 2 - 2 | PSV |
| 2020 2 February | | Eredivisie | Ajax | 1 - 0 | PSV |
| 2019 22 September | | Eredivisie | PSV | 1 - 1 | Ajax |
| 2019 31 March | | Eredivisie | Ajax | 3 - 1 | PSV |
| 2018 23 September | | Eredivisie | PSV | 3 - 0 | Ajax |
| 2018 15 April | | Eredivisie | PSV | 3 - 0 | Ajax |
| 2017 10 December | | Eredivisie | Ajax | 3 - 0 | PSV |
| 2017 23 April | | Eredivisie | PSV | 1 - 0 | Ajax |
| 2016 18 December | | Eredivisie | Ajax | 1 - 1 | PSV |
| 2016 20 March | | Eredivisie | PSV | 0 - 2 | Ajax |
| 2015 4 October | | Eredivisie | Ajax | 1 - 2 | PSV |
| 2015 1 March | | Eredivisie | PSV | 1 - 3 | Ajax |
| 2014 24 August | | Eredivisie | Ajax | 1 - 3 | PSV |
| 2014 19 January | | Eredivisie | Ajax | 1 - 0 | PSV |
| 2013 22 September | | Eredivisie | PSV | 4 - 0 | Ajax |
| 2013 14 April | | Eredivisie | PSV | 2 - 3 | Ajax |
| 2012 1 December | | Eredivisie | Ajax | 3 - 1 | PSV |
| 2012 25 March | | Eredivisie | Ajax | 2 - 0 | PSV |
| 2011 18 September | | Eredivisie | PSV | 2 - 2 | Ajax |
| 2011 27 February | | Eredivisie | PSV | 0 - 0 | Ajax |
| 2010 20 November | | Eredivisie | Ajax | 0 - 0 | PSV |
| 2010 14 March | | Eredivisie | Ajax | 4 - 1 | PSV |
| 2009 16 August | | Eredivisie | PSV | 4 - 3 | Ajax |
| 2009 19 April | | Eredivisie | PSV | 6 - 2 | Ajax |
| 2008 16 November | | Eredivisie | Ajax | 4 - 1 | PSV |
| 2008 19 March | | Eredivisie | PSV | 0 - 0 | Ajax |
| 2008 30 January | | Eredivisie | Ajax | 0 - 2 | PSV |
| 2007 18 March | | Eredivisie | PSV | 1 - 5 | Ajax |
| 2006 12 November | | Eredivisie | Ajax | 0 - 1 | PSV |
| 2006 6 May | | Cup | Ajax | 2 - 1 | PSV |
| 2006 10 March | | Eredivisie | Ajax | 0 - 0 | PSV |
| 2005 22 October | | Eredivisie | PSV | 1 - 0 | Ajax |
| 2005 19 March | | Eredivisie | Ajax | 0 - 4 | PSV |
| 2004 23 October | | Eredivisie | PSV | 2 - 0 | Ajax |
| 2004 7 February | | Eredivisie | Ajax | 2 - 1 | PSV |
| 2003 25 October | | Eredivisie | PSV | 2 - 2 | Ajax |
| 2003 22 March | | Eredivisie | PSV | 2 - 0 | Ajax |
Biggest PSV Eindhoven Victory vs Ajax
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| 2013 22 September | | Eredivisie | PSV | 4 - 0 | Ajax |
Biggest Ajax Victory vs PSV Eindhoven
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| 2021 24 October | | Eredivisie | Ajax | 5 - 0 | PSV |
Biggest PSV Eindhoven Defeat vs Ajax
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| 2021 24 October | | Eredivisie | Ajax | 5 - 0 | PSV |
Biggest Ajax Defeat vs PSV Eindhoven
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| 2013 22 September | | Eredivisie | PSV | 4 - 0 | Ajax |
Last 5 PSV Eindhoven Home Matches
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| 2025 21 October | | UEFA Champions League | PSV | 6 - 2 | Napoli |
| 2025 18 October | | Eredivisie | PSV | 2 - 1 | Go Ahead Eagles |
| 2025 21 September | | Eredivisie | PSV | 2 - 2 | Ajax |
| 2025 16 September | | UEFA Champions League | PSV | 1 - 3 | Union Saint-Gilloise |
| 2025 30 August | | Eredivisie | PSV | 0 - 2 | Telstar |
Last 5 Ajax Home Matches
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| 2025 18 October | | Eredivisie | Ajax | 0 - 2 | AZ |
| 2025 27 September | | Eredivisie | Ajax | 2 - 1 | NAC Breda |
| 2025 17 September | | UEFA Champions League | Ajax | 0 - 2 | Internazionale |
| 2025 13 September | | Eredivisie | Ajax | 3 - 1 | PEC Zwolle |
| 2025 24 August | | Eredivisie | Ajax | 2 - 0 | Heracles |
Last 5 PSV Eindhoven Away Matches
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| 2025 26 October | | Eredivisie | Feyenoord | 2 - 3 | PSV |
| 2025 4 October | | Eredivisie | PEC Zwolle | 0 - 4 | PSV |
| 2025 1 October | | UEFA Champions League | Bayer Leverkusen | 1 - 1 | PSV |
| 2025 27 September | | Eredivisie | Excelsior | 1 - 2 | PSV |
| 2025 13 September | | Eredivisie | NEC | 3 - 5 | PSV |
Last 5 Ajax Away Matches
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| 2025 26 October | | Eredivisie | Twente | 2 - 3 | Ajax |
| 2025 22 October | | UEFA Champions League | Chelsea | 5 - 1 | Ajax |
| 2025 4 October | | Eredivisie | Sparta Rotterdam | 3 - 3 | Ajax |
| 2025 30 September | | UEFA Champions League | Olympique Marseille | 4 - 0 | Ajax |
| 2025 21 September | | Eredivisie | PSV | 2 - 2 | Ajax |