This page lists the head-to-head record of Ajax vs PSV Eindhoven including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | PSV Eindhoven | Ajax | Draws |
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| Total Matches | 67 | 28 | 21 | 18 |
| At Philips Stadion | 35 | 12 | 15 | 8 |
| At Amsterdam Arena | 32 | 16 | 6 | 10 |
| Cup Matches | 4 | 1 | 2 | 1 |
| Eredivisie Matches | 63 | 27 | 19 | 17 |
| Total Goals Scored | 208 | 113 | 95 | |
Last 50 PSV Eindhoven vs Ajax Matches
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| 2024 2 November | | Eredivisie | Ajax | 3 - 2 | PSV |
| 2024 3 February | | Eredivisie | Ajax | 1 - 1 | PSV |
| 2023 29 October | | Eredivisie | PSV | 5 - 2 | Ajax |
| 2023 30 April | | Cup | Ajax | 1 - 1 | PSV |
| 2023 23 April | | Eredivisie | PSV | 3 - 0 | Ajax |
| 2022 6 November | | Eredivisie | Ajax | 1 - 2 | PSV |
| 2022 17 April | | Cup | PSV | 2 - 1 | Ajax |
| 2022 23 January | | Eredivisie | PSV | 1 - 2 | Ajax |
| 2021 24 October | | Eredivisie | Ajax | 5 - 0 | PSV |
| 2021 28 February | | Eredivisie | PSV | 1 - 1 | Ajax |
| 2021 10 February | | Cup | Ajax | 2 - 1 | PSV |
| 2021 10 January | | Eredivisie | Ajax | 2 - 2 | PSV |
| 2020 2 February | | Eredivisie | Ajax | 1 - 0 | PSV |
| 2019 22 September | | Eredivisie | PSV | 1 - 1 | Ajax |
| 2019 31 March | | Eredivisie | Ajax | 3 - 1 | PSV |
| 2018 23 September | | Eredivisie | PSV | 3 - 0 | Ajax |
| 2018 15 April | | Eredivisie | PSV | 3 - 0 | Ajax |
| 2017 10 December | | Eredivisie | Ajax | 3 - 0 | PSV |
| 2017 23 April | | Eredivisie | PSV | 1 - 0 | Ajax |
| 2016 18 December | | Eredivisie | Ajax | 1 - 1 | PSV |
| 2016 20 March | | Eredivisie | PSV | 0 - 2 | Ajax |
| 2015 4 October | | Eredivisie | Ajax | 1 - 2 | PSV |
| 2015 1 March | | Eredivisie | PSV | 1 - 3 | Ajax |
| 2014 24 August | | Eredivisie | Ajax | 1 - 3 | PSV |
| 2014 19 January | | Eredivisie | Ajax | 1 - 0 | PSV |
| 2013 22 September | | Eredivisie | PSV | 4 - 0 | Ajax |
| 2013 14 April | | Eredivisie | PSV | 2 - 3 | Ajax |
| 2012 1 December | | Eredivisie | Ajax | 3 - 1 | PSV |
| 2012 25 March | | Eredivisie | Ajax | 2 - 0 | PSV |
| 2011 18 September | | Eredivisie | PSV | 2 - 2 | Ajax |
| 2011 27 February | | Eredivisie | PSV | 0 - 0 | Ajax |
| 2010 20 November | | Eredivisie | Ajax | 0 - 0 | PSV |
| 2010 14 March | | Eredivisie | Ajax | 4 - 1 | PSV |
| 2009 16 August | | Eredivisie | PSV | 4 - 3 | Ajax |
| 2009 19 April | | Eredivisie | PSV | 6 - 2 | Ajax |
| 2008 16 November | | Eredivisie | Ajax | 4 - 1 | PSV |
| 2008 19 March | | Eredivisie | PSV | 0 - 0 | Ajax |
| 2008 30 January | | Eredivisie | Ajax | 0 - 2 | PSV |
| 2007 18 March | | Eredivisie | PSV | 1 - 5 | Ajax |
| 2006 12 November | | Eredivisie | Ajax | 0 - 1 | PSV |
| 2006 6 May | | Cup | Ajax | 2 - 1 | PSV |
| 2006 10 March | | Eredivisie | Ajax | 0 - 0 | PSV |
| 2005 22 October | | Eredivisie | PSV | 1 - 0 | Ajax |
| 2005 19 March | | Eredivisie | Ajax | 0 - 4 | PSV |
| 2004 23 October | | Eredivisie | PSV | 2 - 0 | Ajax |
| 2004 7 February | | Eredivisie | Ajax | 2 - 1 | PSV |
| 2003 25 October | | Eredivisie | PSV | 2 - 2 | Ajax |
| 2003 22 March | | Eredivisie | PSV | 2 - 0 | Ajax |
| 2002 14 December | | Eredivisie | Ajax | 2 - 4 | PSV |
| 2002 23 March | | Eredivisie | PSV | 1 - 1 | Ajax |
Biggest PSV Eindhoven Victory vs Ajax
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| 2013 22 September | | Eredivisie | PSV | 4 - 0 | Ajax |
Biggest Ajax Victory vs PSV Eindhoven
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| 2021 24 October | | Eredivisie | Ajax | 5 - 0 | PSV |
Biggest PSV Eindhoven Defeat vs Ajax
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| 2021 24 October | | Eredivisie | Ajax | 5 - 0 | PSV |
Biggest Ajax Defeat vs PSV Eindhoven
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| 2013 22 September | | Eredivisie | PSV | 4 - 0 | Ajax |
Last 5 PSV Eindhoven Home Matches
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| 2024 5 November | | UEFA Champions League | PSV | 4 - 0 | Girona |
| 2024 26 October | | Eredivisie | PSV | 6 - 0 | PEC Zwolle |
| 2024 5 October | | Eredivisie | PSV | 2 - 1 | Sparta Rotterdam |
| 2024 1 October | | UEFA Champions League | PSV | 1 - 1 | Sporting Lisbon |
| 2024 14 September | | Eredivisie | PSV | 2 - 0 | NEC |
Last 5 Ajax Home Matches
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| 2024 7 November | | UEFA Europa League | Ajax | 5 - 0 | Maccabi Tel Aviv |
| 2024 2 November | | Eredivisie | Ajax | 3 - 2 | PSV |
| 2024 27 October | | Eredivisie | Ajax | 1 - 0 | Willem II |
| 2024 6 October | | Eredivisie | Ajax | 3 - 1 | Groningen |
| 2024 26 September | | UEFA Europa League | Ajax | 4 - 0 | Besiktas |
Last 5 PSV Eindhoven Away Matches
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| 2024 9 November | | Eredivisie | NAC Breda | 0 - 3 | PSV |
| 2024 2 November | | Eredivisie | Ajax | 3 - 2 | PSV |
| 2024 22 October | | UEFA Champions League | Paris St Germain | 1 - 1 | PSV |
| 2024 19 October | | Eredivisie | AZ | 1 - 2 | PSV |
| 2024 28 September | | Eredivisie | Willem II | 0 - 2 | PSV |
Last 5 Ajax Away Matches
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| 2024 10 November | | Eredivisie | Twente | 2 - 2 | Ajax |
| 2024 30 October | | Eredivisie | Feyenoord | 0 - 2 | Ajax |
| 2024 24 October | | UEFA Europa League | Qarabagh | 0 - 3 | Ajax |
| 2024 20 October | | Eredivisie | Heracles | 3 - 4 | Ajax |
| 2024 3 October | | UEFA Europa League | Slavia Praha | 1 - 1 | Ajax |