This page lists the head-to-head record of Livorno vs Napoli including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | Napoli | Livorno | Draws |
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| Total Matches | 11 | 5 | 2 | 4 |
| At Stadio San Paolo | 5 | 2 | 1 | 2 |
| At Stadio Armando Picchi | 6 | 3 | 1 | 2 |
| Cup Matches | 1 | 0 | 0 | 1 |
| Serie B Matches | 4 | 0 | 2 | 2 |
| Serie A Matches | 6 | 5 | 0 | 1 |
| Total Goals Scored | 24 | 15 | 9 | |
Last 50 Napoli vs Livorno Matches
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| 2014 2 March | | Serie A | Livorno | 1 - 1 | Napoli |
| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
| 2010 24 January | | Serie A | Livorno | 0 - 2 | Napoli |
| 2009 30 August | | Serie A | Napoli | 3 - 1 | Livorno |
| 2008 24 February | | Serie A | Livorno | 1 - 2 | Napoli |
| 2007 26 September | | Serie A | Napoli | 1 - 0 | Livorno |
| 2007 29 August | | Cup | Napoli | 1 - 1 | Livorno |
| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
| 2003 11 October | | Serie B | Napoli | 0 - 0 | Livorno |
| 2003 22 March | | Serie B | Livorno | 1 - 1 | Napoli |
| 2002 18 October | | Serie B | Napoli | 0 - 1 | Livorno |
Biggest Napoli Victory vs Livorno
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| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
Biggest Livorno Victory vs Napoli
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| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
Biggest Napoli Defeat vs Livorno
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| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
Biggest Livorno Defeat vs Napoli
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| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
Last 5 Napoli Home Matches
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| 2025 25 November | | UEFA Champions League | Napoli | 2 - 0 | Qarabagh |
| 2025 22 November | | Serie A | Napoli | 3 - 1 | Atalanta |
| 2025 4 November | | UEFA Champions League | Napoli | 0 - 0 | Eintracht Frankfurt |
| 2025 1 November | | Serie A | Napoli | 0 - 0 | Como |
| 2025 25 October | | Serie A | Napoli | 3 - 1 | Internazionale |
Last 5 Livorno Home Matches
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| 2025 24 November | | Serie C1 - A | Livorno | 3 - 1 | Torres |
| 2025 16 November | | Serie C1 - A | Livorno | 1 - 1 | Ravenna |
| 2025 2 November | | Serie C1 - A | Livorno | 2 - 3 | Forli' |
| 2025 18 October | | Serie C1 - A | Livorno | 2 - 1 | Sambenedettese |
| 2025 27 September | | Serie C1 - A | Livorno | 0 - 0 | Citta di Campobasso |
Last 5 Napoli Away Matches
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| 2025 9 November | | Serie A | Bologna | 2 - 0 | Napoli |
| 2025 28 October | | Serie A | Lecce | 0 - 1 | Napoli |
| 2025 21 October | | UEFA Champions League | PSV | 6 - 2 | Napoli |
| 2025 18 October | | Serie A | Torino | 1 - 0 | Napoli |
| 2025 28 September | | Serie A | Milan | 2 - 1 | Napoli |
Last 5 Livorno Away Matches
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| 2025 9 November | | Serie C1 - A | Athletic Carpi | 2 - 0 | Livorno |
| 2025 27 October | | Serie C1 - A | Perugia | 2 - 0 | Livorno |
| 2025 11 October | | Serie C1 - A | Pineto | 3 - 0 | Livorno |
| 2025 3 October | | Serie C1 - A | Pianese | 2 - 1 | Livorno |
| 2025 23 September | | Serie C1 - A | Bra | 0 - 1 | Livorno |