This page lists the head-to-head record of Livorno vs Napoli including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | Napoli | Livorno | Draws |
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| Total Matches | 11 | 5 | 2 | 4 |
| At Stadio San Paolo | 5 | 2 | 1 | 2 |
| At Stadio Armando Picchi | 6 | 3 | 1 | 2 |
| Cup Matches | 1 | 0 | 0 | 1 |
| Serie B Matches | 4 | 0 | 2 | 2 |
| Serie A Matches | 6 | 5 | 0 | 1 |
| Total Goals Scored | 24 | 15 | 9 | |
Last 50 Napoli vs Livorno Matches
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| 2014 2 March | | Serie A | Livorno | 1 - 1 | Napoli |
| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
| 2010 24 January | | Serie A | Livorno | 0 - 2 | Napoli |
| 2009 30 August | | Serie A | Napoli | 3 - 1 | Livorno |
| 2008 24 February | | Serie A | Livorno | 1 - 2 | Napoli |
| 2007 26 September | | Serie A | Napoli | 1 - 0 | Livorno |
| 2007 29 August | | Cup | Napoli | 1 - 1 | Livorno |
| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
| 2003 11 October | | Serie B | Napoli | 0 - 0 | Livorno |
| 2003 22 March | | Serie B | Livorno | 1 - 1 | Napoli |
| 2002 18 October | | Serie B | Napoli | 0 - 1 | Livorno |
Biggest Napoli Victory vs Livorno
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| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
Biggest Livorno Victory vs Napoli
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| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
Biggest Napoli Defeat vs Livorno
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| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
Biggest Livorno Defeat vs Napoli
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| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
Last 5 Napoli Home Matches
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| 2025 7 December | | Serie A | Napoli | 2 - 1 | Juventus |
| 2025 3 December | | Cup | Napoli | 1 - 1 | Cagliari |
| 2025 25 November | | UEFA Champions League | Napoli | 2 - 0 | Qarabagh |
| 2025 22 November | | Serie A | Napoli | 3 - 1 | Atalanta |
| 2025 4 November | | UEFA Champions League | Napoli | 0 - 0 | Eintracht Frankfurt |
Last 5 Livorno Home Matches
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| 2025 20 December | | Serie C1 - A | Livorno | 2 - 2 | Pontedera |
| 2025 6 December | | Serie C1 - A | Livorno | 2 - 1 | Arezzo |
| 2025 24 November | | Serie C1 - A | Livorno | 3 - 1 | Torres |
| 2025 16 November | | Serie C1 - A | Livorno | 1 - 1 | Ravenna |
| 2025 2 November | | Serie C1 - A | Livorno | 2 - 3 | Forli' |
Last 5 Napoli Away Matches
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| 2026 4 January | | Serie A | Lazio | 0 - 2 | Napoli |
| 2025 28 December | | Serie A | Cremonese | 0 - 2 | Napoli |
| 2025 14 December | | Serie A | Udinese | 1 - 0 | Napoli |
| 2025 10 December | | UEFA Champions League | Benfica | 2 - 0 | Napoli |
| 2025 30 November | | Serie A | Roma | 0 - 1 | Napoli |
Last 5 Livorno Away Matches
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| 2026 4 January | | Serie C1 - A | Ternana | 2 - 1 | Livorno |
| 2025 29 November | | Serie C1 - A | Gubbio | 0 - 0 | Livorno |
| 2025 9 November | | Serie C1 - A | Athletic Carpi | 2 - 0 | Livorno |
| 2025 27 October | | Serie C1 - A | Perugia | 2 - 0 | Livorno |
| 2025 11 October | | Serie C1 - A | Pineto | 3 - 0 | Livorno |