This page lists the head-to-head record of Napoli vs Livorno including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | Livorno | Napoli | Draws |
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| Total Matches | 11 | 2 | 5 | 4 |
| At Stadio Armando Picchi | 6 | 1 | 3 | 2 |
| At Stadio San Paolo | 5 | 1 | 2 | 2 |
| Cup Matches | 1 | 0 | 0 | 1 |
| Serie B Matches | 4 | 2 | 0 | 2 |
| Serie A Matches | 6 | 0 | 5 | 1 |
| Total Goals Scored | 24 | 9 | 15 | |
Last 50 Livorno vs Napoli Matches
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| 2014 2 March | | Serie A | Livorno | 1 - 1 | Napoli |
| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
| 2010 24 January | | Serie A | Livorno | 0 - 2 | Napoli |
| 2009 30 August | | Serie A | Napoli | 3 - 1 | Livorno |
| 2008 24 February | | Serie A | Livorno | 1 - 2 | Napoli |
| 2007 26 September | | Serie A | Napoli | 1 - 0 | Livorno |
| 2007 29 August | | Cup | Napoli | 1 - 1 | Livorno |
| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
| 2003 11 October | | Serie B | Napoli | 0 - 0 | Livorno |
| 2003 22 March | | Serie B | Livorno | 1 - 1 | Napoli |
| 2002 18 October | | Serie B | Napoli | 0 - 1 | Livorno |
Biggest Livorno Victory vs Napoli
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| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
Biggest Napoli Victory vs Livorno
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| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
Biggest Livorno Defeat vs Napoli
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| 2013 6 October | | Serie A | Napoli | 4 - 0 | Livorno |
Biggest Napoli Defeat vs Livorno
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| 2004 6 March | | Serie B | Livorno | 3 - 0 | Napoli |
Last 5 Livorno Home Matches
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| 2025 27 September | | Serie C1 - A | Livorno | 0 - 0 | Citta di Campobasso |
| 2025 20 September | | Serie C1 - A | Livorno | 0 - 3 | Ascoli Picchio |
| 2025 7 September | | Serie C1 - A | Livorno | 0 - 1 | Nuova Monterosi |
| 2025 22 August | | Serie C1 - A | Livorno | 1 - 0 | Ternana |
| 2021 2 May | | Serie C1 - A | Livorno | 0 - 2 | Pro Sesto |
Last 5 Napoli Home Matches
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| 2025 5 October | | Serie A | Napoli | 2 - 1 | Genoa |
| 2025 1 October | | UEFA Champions League | Napoli | 2 - 1 | Sporting Lisbon |
| 2025 22 September | | Serie A | Napoli | 3 - 2 | Pisa |
| 2025 30 August | | Serie A | Napoli | 1 - 0 | Cagliari |
| 2025 23 May | | Serie A | Napoli | 2 - 0 | Cagliari |
Last 5 Livorno Away Matches
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| 2025 3 October | | Serie C1 - A | Pianese | 2 - 1 | Livorno |
| 2025 23 September | | Serie C1 - A | Bra | 0 - 1 | Livorno |
| 2025 14 September | | Serie C1 - A | Vis Pesaro | 3 - 0 | Livorno |
| 2025 30 August | | Serie C1 - A | Juventus II | 2 - 1 | Livorno |
| 2021 25 April | | Serie C1 - A | Pro Patria | 2 - 2 | Livorno |
Last 5 Napoli Away Matches
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| 2025 28 September | | Serie A | Milan | 2 - 1 | Napoli |
| 2025 18 September | | UEFA Champions League | Manchester City | 2 - 0 | Napoli |
| 2025 13 September | | Serie A | Fiorentina | 1 - 3 | Napoli |
| 2025 23 August | | Serie A | Sassuolo | 0 - 2 | Napoli |
| 2025 18 May | | Serie A | Parma | 0 - 0 | Napoli |