This page lists the head-to-head record of Napoli vs Grosseto including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | Grosseto | Napoli | Draws |
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| Total Matches | 2 | 0 | 0 | 2 |
| At Stadio Carlo Zecchini | 1 | 0 | 0 | 1 |
| At Stadio San Paolo | 1 | 0 | 0 | 1 |
| Serie C1 - A Matches | 2 | 0 | 0 | 2 |
| Total Goals Scored | 6 | 3 | 3 | |
Last 50 Grosseto vs Napoli Matches
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| 2006 22 April | | Serie C1 - A | Grosseto | 2 - 2 | Napoli |
| 2006 4 January | | Serie C1 - A | Napoli | 1 - 1 | Grosseto |
Last 5 Grosseto Home Matches
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| 2022 14 April | | Serie C1 - A | Grosseto | 0 - 2 | Lucchese |
| 2022 3 April | | Serie C1 - A | Grosseto | 0 - 0 | Robur Siena |
| 2022 19 March | | Serie C1 - A | Grosseto | 1 - 0 | Virtus Entella |
| 2022 15 March | | Serie C1 - A | Grosseto | 0 - 0 | Pontedera |
| 2022 6 March | | Serie C1 - A | Grosseto | 2 - 0 | Imolese |
Last 5 Napoli Home Matches
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| 2025 25 October | | Serie A | Napoli | 3 - 1 | Internazionale |
| 2025 5 October | | Serie A | Napoli | 2 - 1 | Genoa |
| 2025 1 October | | UEFA Champions League | Napoli | 2 - 1 | Sporting Lisbon |
| 2025 22 September | | Serie A | Napoli | 3 - 2 | Pisa |
| 2025 30 August | | Serie A | Napoli | 1 - 0 | Cagliari |
Last 5 Grosseto Away Matches
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| 2022 23 April | | Serie C1 - A | Olbia | 3 - 1 | Grosseto |
| 2022 9 April | | Serie C1 - A | Pescara | 2 - 1 | Grosseto |
| 2022 27 March | | Serie C1 - A | Montevarchi Calcio | 1 - 1 | Grosseto |
| 2022 12 March | | Serie C1 - A | Vis Pesaro | 2 - 1 | Grosseto |
| 2022 27 February | | Serie C1 - A | Teramo | 2 - 1 | Grosseto |
Last 5 Napoli Away Matches
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| 2025 21 October | | UEFA Champions League | PSV | 6 - 2 | Napoli |
| 2025 18 October | | Serie A | Torino | 1 - 0 | Napoli |
| 2025 28 September | | Serie A | Milan | 2 - 1 | Napoli |
| 2025 18 September | | UEFA Champions League | Manchester City | 2 - 0 | Napoli |
| 2025 13 September | | Serie A | Fiorentina | 1 - 3 | Napoli |