This page lists the head-to-head record of 1.FC Union Berlin vs FSV Mainz including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | FSV Mainz | 1.FC Union Berlin | Draws |
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| Total Matches | 16 | 5 | 7 | 4 |
| At Opel Arena | 8 | 1 | 5 | 2 |
| At Stadion An der Alten Forsterei | 8 | 4 | 2 | 2 |
| Bundesliga 2 Matches | 6 | 4 | 1 | 1 |
| Bundesliga Matches | 10 | 1 | 6 | 3 |
| Total Goals Scored | 42 | 17 | 25 | |
Last 50 FSV Mainz vs 1.FC Union Berlin Matches
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| 2024 7 February | | Bundesliga | Mainz 05 | 1 - 1 | Union Berlin |
| 2023 20 August | | Bundesliga | Union Berlin | 4 - 1 | Mainz 05 |
| 2023 4 February | | Bundesliga | Union Berlin | 2 - 1 | Mainz 05 |
| 2022 14 August | | Bundesliga | Mainz 05 | 0 - 0 | Union Berlin |
| 2022 26 February | | Bundesliga | Union Berlin | 3 - 1 | Mainz 05 |
| 2021 3 October | | Bundesliga | Mainz 05 | 1 - 2 | Union Berlin |
| 2021 6 February | | Bundesliga | Mainz 05 | 1 - 0 | Union Berlin |
| 2020 2 October | | Bundesliga | Union Berlin | 4 - 0 | Mainz 05 |
| 2020 27 May | | Bundesliga | Union Berlin | 1 - 1 | Mainz 05 |
| 2019 9 November | | Bundesliga | Mainz 05 | 2 - 3 | Union Berlin |
| 2004 31 January | | Bundesliga 2 | Union Berlin | 1 - 1 | Mainz 05 |
| 2003 2 August | | Bundesliga 2 | Mainz 05 | 2 - 1 | Union Berlin |
| 2003 25 January | | Bundesliga 2 | Mainz 05 | 1 - 0 | Union Berlin |
| 2002 9 August | | Bundesliga 2 | Union Berlin | 0 - 2 | Mainz 05 |
| 2002 4 May | | Bundesliga 2 | Union Berlin | 3 - 1 | Mainz 05 |
| 2001 15 December | | Bundesliga 2 | Mainz 05 | 1 - 0 | Union Berlin |
Biggest FSV Mainz Victory vs 1.FC Union Berlin
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| 2002 9 August | | Bundesliga 2 | Union Berlin | 0 - 2 | Mainz 05 |
Biggest 1.FC Union Berlin Victory vs FSV Mainz
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| 2020 2 October | | Bundesliga | Union Berlin | 4 - 0 | Mainz 05 |
Biggest FSV Mainz Defeat vs 1.FC Union Berlin
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| 2020 2 October | | Bundesliga | Union Berlin | 4 - 0 | Mainz 05 |
Biggest 1.FC Union Berlin Defeat vs FSV Mainz
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| 2002 9 August | | Bundesliga 2 | Union Berlin | 0 - 2 | Mainz 05 |
Last 5 FSV Mainz Home Matches
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| 2024 13 April | | Bundesliga | Mainz 05 | 4 - 1 | Hoffenheim |
| 2024 6 April | | Bundesliga | Mainz 05 | 4 - 0 | Darmstadt 98 |
| 2024 16 March | | Bundesliga | Mainz 05 | 2 - 0 | Bochum |
| 2024 2 March | | Bundesliga | Mainz 05 | 1 - 1 | Borussia M'gladbach |
| 2024 17 February | | Bundesliga | Mainz 05 | 1 - 0 | Augsburg |
Last 5 1.FC Union Berlin Home Matches
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| 2024 6 April | | Bundesliga | Union Berlin | 0 - 1 | Bayer Leverkusen |
| 2024 16 March | | Bundesliga | Union Berlin | 2 - 1 | Werder Bremen |
| 2024 2 March | | Bundesliga | Union Berlin | 0 - 2 | Borussia Dortmund |
| 2024 24 February | | Bundesliga | Union Berlin | 2 - 2 | Heidenheim |
| 2024 10 February | | Bundesliga | Union Berlin | 1 - 0 | Wolfsburg |
Last 5 FSV Mainz Away Matches
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| 2024 30 March | | Bundesliga | RB Leipzig | 0 - 0 | Mainz 05 |
| 2024 9 March | | Bundesliga | Bayern Munchen | 8 - 1 | Mainz 05 |
| 2024 23 February | | Bundesliga | Bayer Leverkusen | 2 - 1 | Mainz 05 |
| 2024 11 February | | Bundesliga | Stuttgart | 3 - 1 | Mainz 05 |
| 2024 26 January | | Bundesliga | Eintracht Frankfurt | 1 - 0 | Mainz 05 |
Last 5 1.FC Union Berlin Away Matches
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| 2024 12 April | | Bundesliga | Augsburg | 2 - 0 | Union Berlin |
| 2024 30 March | | Bundesliga | Eintracht Frankfurt | 0 - 0 | Union Berlin |
| 2024 8 March | | Bundesliga | Stuttgart | 2 - 0 | Union Berlin |
| 2024 17 February | | Bundesliga | Hoffenheim | 0 - 1 | Union Berlin |
| 2024 7 February | | Bundesliga | Mainz 05 | 1 - 1 | Union Berlin |