This page lists the head-to-head record of 1.FC Union Berlin vs FSV Mainz including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | FSV Mainz | 1.FC Union Berlin | Draws |
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| Total Matches | 17 | 5 | 7 | 5 |
| At Opel Arena | 8 | 1 | 5 | 2 |
| At Stadion An der Alten Forsterei | 9 | 4 | 2 | 3 |
| Bundesliga 2 Matches | 6 | 4 | 1 | 1 |
| Bundesliga Matches | 11 | 1 | 6 | 4 |
| Total Goals Scored | 44 | 18 | 26 | |
Last 50 FSV Mainz vs 1.FC Union Berlin Matches
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| 2024 24 August | | Bundesliga | Mainz 05 | 1 - 1 | Union Berlin |
| 2024 7 February | | Bundesliga | Mainz 05 | 1 - 1 | Union Berlin |
| 2023 20 August | | Bundesliga | Union Berlin | 4 - 1 | Mainz 05 |
| 2023 4 February | | Bundesliga | Union Berlin | 2 - 1 | Mainz 05 |
| 2022 14 August | | Bundesliga | Mainz 05 | 0 - 0 | Union Berlin |
| 2022 26 February | | Bundesliga | Union Berlin | 3 - 1 | Mainz 05 |
| 2021 3 October | | Bundesliga | Mainz 05 | 1 - 2 | Union Berlin |
| 2021 6 February | | Bundesliga | Mainz 05 | 1 - 0 | Union Berlin |
| 2020 2 October | | Bundesliga | Union Berlin | 4 - 0 | Mainz 05 |
| 2020 27 May | | Bundesliga | Union Berlin | 1 - 1 | Mainz 05 |
| 2019 9 November | | Bundesliga | Mainz 05 | 2 - 3 | Union Berlin |
| 2004 31 January | | Bundesliga 2 | Union Berlin | 1 - 1 | Mainz 05 |
| 2003 2 August | | Bundesliga 2 | Mainz 05 | 2 - 1 | Union Berlin |
| 2003 25 January | | Bundesliga 2 | Mainz 05 | 1 - 0 | Union Berlin |
| 2002 9 August | | Bundesliga 2 | Union Berlin | 0 - 2 | Mainz 05 |
| 2002 4 May | | Bundesliga 2 | Union Berlin | 3 - 1 | Mainz 05 |
| 2001 15 December | | Bundesliga 2 | Mainz 05 | 1 - 0 | Union Berlin |
Biggest FSV Mainz Victory vs 1.FC Union Berlin
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| 2002 9 August | | Bundesliga 2 | Union Berlin | 0 - 2 | Mainz 05 |
Biggest 1.FC Union Berlin Victory vs FSV Mainz
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| 2020 2 October | | Bundesliga | Union Berlin | 4 - 0 | Mainz 05 |
Biggest FSV Mainz Defeat vs 1.FC Union Berlin
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| 2020 2 October | | Bundesliga | Union Berlin | 4 - 0 | Mainz 05 |
Biggest 1.FC Union Berlin Defeat vs FSV Mainz
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| 2002 9 August | | Bundesliga 2 | Union Berlin | 0 - 2 | Mainz 05 |
Last 5 FSV Mainz Home Matches
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| 2024 28 September | | Bundesliga | Mainz 05 | 0 - 2 | Heidenheim |
| 2024 15 September | | Bundesliga | Mainz 05 | 1 - 2 | Werder Bremen |
| 2024 24 August | | Bundesliga | Mainz 05 | 1 - 1 | Union Berlin |
| 2024 11 May | | Bundesliga | Mainz 05 | 3 - 0 | Borussia Dortmund |
| 2024 28 April | | Bundesliga | Mainz 05 | 1 - 1 | FC Koln |
Last 5 1.FC Union Berlin Home Matches
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| 2024 21 September | | Bundesliga | Union Berlin | 2 - 1 | Hoffenheim |
| 2024 30 August | | Bundesliga | Union Berlin | 1 - 0 | St. Pauli |
| 2024 18 May | | Bundesliga | Union Berlin | 2 - 1 | Freiburg |
| 2024 5 May | | Bundesliga | Union Berlin | 3 - 4 | Bochum |
| 2024 20 April | | Bundesliga | Union Berlin | 1 - 5 | Bayern Munchen |
Last 5 FSV Mainz Away Matches
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| 2024 20 September | | Bundesliga | Augsburg | 2 - 3 | Mainz 05 |
| 2024 31 August | | Bundesliga | Stuttgart | 3 - 3 | Mainz 05 |
| 2024 16 August | | Cup | Wehen Wiesbaden | 1 - 1 | Mainz 05 |
| 2024 18 May | | Bundesliga | Wolfsburg | 1 - 3 | Mainz 05 |
| 2024 5 May | | Bundesliga | Heidenheim | 1 - 1 | Mainz 05 |
Last 5 1.FC Union Berlin Away Matches
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| 2024 28 September | | Bundesliga | Borussia M'gladbach | 1 - 0 | Union Berlin |
| 2024 14 September | | Bundesliga | RB Leipzig | 0 - 0 | Union Berlin |
| 2024 24 August | | Bundesliga | Mainz 05 | 1 - 1 | Union Berlin |
| 2024 17 August | | Cup | Greifswalder FC | 0 - 1 | Union Berlin |
| 2024 11 May | | Bundesliga | FC Koln | 3 - 2 | Union Berlin |