This page lists the head-to-head record of Rio Ave vs CD Nacional including biggest victories and defeats between the two sides, and H2H stats in all competitions.
Overall H2H Record - Summary
| Total | CD Nacional | Rio Ave | Draws |
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| Total Matches | 34 | 12 | 11 | 11 |
| At Est·dio da Madeira | 17 | 5 | 8 | 4 |
| At Estádio dos Arcos | 17 | 7 | 3 | 7 |
| Division2 Matches | 4 | 3 | 1 | 0 |
| Portuguese Liga Matches | 28 | 8 | 9 | 11 |
| Segunda Liga Matches | 2 | 1 | 1 | 0 |
| Total Goals Scored | 68 | 38 | 30 | |
Last 50 CD Nacional vs Rio Ave Matches
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| 2022 10 April | | Segunda Liga | Nacional | 2 - 0 | Rio Ave |
| 2021 28 November | | Segunda Liga | Rio Ave | 1 - 0 | Nacional |
| 2021 19 May | | Portuguese Liga | Nacional | 1 - 2 | Rio Ave |
| 2021 5 February | | Portuguese Liga | Rio Ave | 0 - 0 | Nacional |
| 2019 17 March | | Portuguese Liga | Nacional | 0 - 1 | Rio Ave |
| 2018 5 November | | Portuguese Liga | Rio Ave | 3 - 3 | Nacional |
| 2017 29 April | | Portuguese Liga | Nacional | 0 - 2 | Rio Ave |
| 2016 18 December | | Portuguese Liga | Rio Ave | 2 - 1 | Nacional |
| 2016 13 March | | Portuguese Liga | Nacional | 1 - 0 | Rio Ave |
| 2015 1 November | | Portuguese Liga | Rio Ave | 1 - 0 | Nacional |
| 2015 9 March | | Portuguese Liga | Rio Ave | 1 - 1 | Nacional |
| 2014 5 October | | Portuguese Liga | Nacional | 0 - 0 | Rio Ave |
| 2014 2 March | | Portuguese Liga | Nacional | 1 - 1 | Rio Ave |
| 2013 28 September | | Portuguese Liga | Rio Ave | 0 - 3 | Nacional |
| 2013 10 March | | Portuguese Liga | Nacional | 1 - 1 | Rio Ave |
| 2012 28 October | | Portuguese Liga | Rio Ave | 2 - 1 | Nacional |
| 2012 1 April | | Portuguese Liga | Nacional | 2 - 1 | Rio Ave |
| 2011 6 November | | Portuguese Liga | Rio Ave | 2 - 1 | Nacional |
| 2011 16 January | | Portuguese Liga | Nacional | 1 - 0 | Rio Ave |
| 2010 15 August | | Portuguese Liga | Rio Ave | 0 - 1 | Nacional |
| 2010 14 February | | Portuguese Liga | Nacional | 1 - 1 | Rio Ave |
| 2009 12 September | | Portuguese Liga | Rio Ave | 2 - 0 | Nacional |
| 2009 6 April | | Portuguese Liga | Rio Ave | 0 - 3 | Nacional |
| 2008 16 November | | Portuguese Liga | Nacional | 0 - 0 | Rio Ave |
| 2006 24 March | | Portuguese Liga | Nacional | 1 - 1 | Rio Ave |
| 2005 19 November | | Portuguese Liga | Rio Ave | 0 - 2 | Nacional |
| 2005 16 April | | Portuguese Liga | Nacional | 0 - 0 | Rio Ave |
| 2004 27 November | | Portuguese Liga | Rio Ave | 4 - 1 | Nacional |
| 2004 8 May | | Portuguese Liga | Nacional | 4 - 0 | Rio Ave |
| 2004 9 January | | Portuguese Liga | Rio Ave | 0 - 0 | Nacional |
| 2002 9 March | | Division2 | Rio Ave | 0 - 1 | Nacional |
| 2001 20 October | | Division2 | Nacional | 2 - 0 | Rio Ave |
| 2001 17 March | | Division2 | Rio Ave | 2 - 0 | Nacional |
| 2000 21 October | | Division2 | Nacional | 3 - 0 | Rio Ave |
Biggest CD Nacional Victory vs Rio Ave
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| 2004 8 May | | Portuguese Liga | Nacional | 4 - 0 | Rio Ave |
Biggest Rio Ave Victory vs CD Nacional
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| 2004 27 November | | Portuguese Liga | Rio Ave | 4 - 1 | Nacional |
Biggest CD Nacional Defeat vs Rio Ave
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| 2004 27 November | | Portuguese Liga | Rio Ave | 4 - 1 | Nacional |
Biggest Rio Ave Defeat vs CD Nacional
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| 2004 8 May | | Portuguese Liga | Nacional | 4 - 0 | Rio Ave |
Last 5 CD Nacional Home Matches
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| 2024 6 April | | Segunda Liga | Nacional | 2 - 1 | AVS |
| 2024 9 March | | Segunda Liga | Nacional | 1 - 1 | Academico Viseu |
| 2024 24 February | | Segunda Liga | Nacional | 3 - 2 | Penafiel |
| 2024 10 February | | Segunda Liga | Nacional | 3 - 2 | Vilaverdense |
| 2024 28 January | | Segunda Liga | Nacional | 2 - 1 | Torreense |
Last 5 Rio Ave Home Matches
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| 2024 6 April | | Portuguese Liga | Rio Ave | 3 - 0 | Gil Vicente |
| 2024 9 March | | Portuguese Liga | Rio Ave | 0 - 0 | Sporting Braga |
| 2024 25 February | | Portuguese Liga | Rio Ave | 3 - 3 | Sporting Lisbon |
| 2024 11 February | | Portuguese Liga | Rio Ave | 1 - 0 | Casa Pia |
| 2024 31 January | | Portuguese Liga | Rio Ave | 1 - 1 | Estoril |
Last 5 CD Nacional Away Matches
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| 2024 14 April | | Segunda Liga | Pacos de Ferreira | 1 - 1 | Nacional |
| 2024 30 March | | Segunda Liga | Uniao de Leiria | 1 - 1 | Nacional |
| 2024 17 March | | Segunda Liga | Santa Clara | 0 - 1 | Nacional |
| 2024 3 March | | Segunda Liga | UD Oliveirense | 0 - 1 | Nacional |
| 2024 28 February | | Segunda Liga | Leixoes | 1 - 1 | Nacional |
Last 5 Rio Ave Away Matches
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| 2024 14 April | | Portuguese Liga | Estrela P | 2 - 2 | Rio Ave |
| 2024 30 March | | Portuguese Liga | Boavista | 0 - 0 | Rio Ave |
| 2024 16 March | | Portuguese Liga | Farense | 1 - 1 | Rio Ave |
| 2024 2 March | | Portuguese Liga | Moreirense | 0 - 0 | Rio Ave |
| 2024 16 February | | Portuguese Liga | Famalicao | 2 - 1 | Rio Ave |